First of all, I should have know the mechanics of the stove prior to lighting. That should go without saying for all projects but often can take some of the fun out of it. Anyway, the stove works using the can to direct the flow of heat and pressure of the fuel and its vapors. To that end, the penny acts as a valve. When it is sitting at normal state the penny creates enough tension so that the fuel doesn't drain into the cup allowing you to light it. Once lit, the flame heats up the aluminum burner, fuel cup, and liquid fuel. Due to the differences between the aluminum and copper (or zinc, I should say), the heated aluminum creates a space between the penny and the burner allowing the now-heated fuel to slip down into the cup. The fuel boils in the cup, vaporizes, and presses out the path of least resistance which is through the keys on the outer ring of the burner. As the vapor sprays out of the keys it comes in contact with the lit priming fuel and combusts.
Having found out how the stove works and how to light it, I made sure to get some denatured alcohol (because pure grain alcohol is illegal in this state - figures) and I also wanted to find something out of which to build my pot stand. I found exactly what I'd been looking for at my trusty ACE hardware. Denatured alcohol is basically pure alcohol with additives that render it undrinkable but it's used as a solvent. I also found some metal skewers
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